Answer: Based only on vapor pressure data, ethyl ether (vapor pressure at 293 K = 450 torr) has the weakest intermolecular attractions. The correct option is B.
Explanation:
Vapour pressure can be defined as the pressure created by vapour of a substance( gas or liquid) in thermodynamic equilibrium state in a closed container at a certain temperature.
Factor which affects the vapour pressure of a substance includes:
- surface area
- intermolecular forces and
- temperature.
Strong intermolecular attractions between molecules in a medium produce a lower rate of evaporation and a lower vapour pressure. While weak intermolecular attraction between molecules in a medium produce a higher rate of evaporation and a higher vapour pressure.
From the options listed above, ethyl ether has the highest vapour pressure at the same temperature with others, therefore it will have the weakest intermolecular attractions.
